From Gray to Green: An Aerosol Journey in the Amazon

The Science

Aerosols—tiny particles in the air—have important effects on the Earth’s energy balance and water cycle. The majority of the aerosol mass is made up of organic compounds that formed from precursor compounds released by plants and human activities. Understanding how precursor compounds evolve in the atmosphere and eventually end up as aerosol particles, and representing these processes in models, is one of the more complex challenges in atmospheric science. Using airborne data from the Green Ocean Amazon (GoAmazon 2014/5) field campaign, a research team led by scientists at the U.S. Department of Energy’s (DOE) Pacific Northwest National Laboratory collected and analyzed measurements of the chemical composition, sources, and evolution of aerosol in the urban plume from Manaus, Brazil, as it moved into the surrounding Amazon forest. The data analysis showed changes in the aerosol chemical properties as the plume moved downwind. The measurements also suggested that formation of organic aerosol in the Manaus plume occurred, at least in part, by a mechanism different from that seen in North American cities.

The Impact

Measurements obtained from the DOE Atmospheric Radiation Measurement (ARM) user facility’s Gulfstream-159 (G-1) research aircraft during GoAmazon provide a unique set of observations for understanding aerosol chemistry. When compared to the outflow of many North American cities, the analysis showed that aging of the Manaus plume generated less organic aerosol downwind during the wet season. These results have implications for modeling efforts and for understanding how urban pollution evolves in different environments.

Summary

To date, most field studies of organic aerosol evolution have been conducted in the Northern Hemisphere. Far fewer studies have been performed in the Southern Hemisphere, where there is less land mass, fewer people, and therefore lower background concentrations of pollutants. GoAmazon G-1 deployments took place from February to March 2014 (wet season) and September to October 2014 (dry season). Researchers studied G-1 measurements of aerosol chemical composition and secondary organic aerosol formation and aging within the Manaus plume. The team found that, on average, organics dominated the particle chemical composition, constituting 80 percent of the total aerosol mass in both the wet and dry seasons. Sulfate constituted 14 percent, nitrate 2 percent, and ammonium 4 percent. This distribution was unchanged between seasons, despite significantly higher aerosol concentrations in the dry season.

When examining organic aerosol aging in the Manaus plume, researchers observed oxidation of organic particles and conversion of reduced organic aerosol to oxidized organic aerosol. Despite these changes in aerosol chemical composition, ?org/? CO—a measure of the production of organic aerosol—was constant with aging because of the balance between the formation of oxidized, secondary organic aerosol and the loss of reduced, primary organic aerosol that is directly emitted into the atmosphere. Observations of constant ?org/? CO contrasted with literature studies of the outflow of many North American cities, which reported significant increases in ?org/? CO for the first day of plume aging. The difference was likely due to a combination of factors, including differences in emissions from Manaus and the surrounding tropical forest, lower levels of background pollution in the Amazon, and lower background organic aerosol concentrations.

Principal Investigator(s)

John Shilling
Pacific Northwest National Laboratory
[email protected]

Funding

Funding for data collection onboard the G-1 aircraft and at the ground sites was provided by the Atmospheric Radiation Measurement (ARM) Climate Research Facility, a U.S. Department of Energy (DOE) Office of Science user facility sponsored by the Office of Biological and Environmental Research. Data analysis and research was supported by DOE’s Atmospheric System Research program under Contract DE-AC06-76RLO 1830 at PNNL. Researchers acknowledge the support from the Central Office of the Large Scale Biosphere Atmosphere Experiment in Amazonia (LBA), the Instituto Nacional de Pesquisas da Amazonia (INPA), and the Instituto Nacional de Pesquisas Espaciais (INPE). P. Artaxo acknowledges Fundação de Amparo à Pesquisa do Estado de São Paulo FAPESP grants 2013/05014-0 and 2017/17047-0. The work was conducted under licenses 001262/2012-2 and 001030/2012-4 of the Brazilian National Council for Scientific and Technological Development (CNPq).

References

Shilling, J.E., M.S. Pekour, E.C. Fortner, P. Artaxo, S. de Sá, J.M. Hubbe, K.M. Longo, L.A.T. Machado, S.T. Martin, S.R. Springston, J. Tomlinson, J. Wang. “Aircraft Observations of the Chemical Composition and Aging of Aerosol in the Manaus Urban Plume during GoAmazon 2014/5.” Atmospheric Chemistry and Physics 18, 10773-10797 (2018). DOI:10.5194/acp-18-10773-2018